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  1. The boiling point is determined by the Vander waal force, which increases with increasing size. The boiling points of 15 group hydrides are listed in the following order: BiH3 > SbH3 > NH3 > AsH3 > PH3 (i) Because of hydrogen bonding, ammonia has a higher boiling point than phosphine in the case of NH3 and PH3.
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    The correct order of boiling point of group 15 hydrides is P H3 <AsH3 < N H3 < SbH3< BiH3.
    byjus.com/question-answer/assertion-the-boiling-p…
    The increasing order of boiling point of hydrides of group 15 elements is A PH 3<AsH 3<NH 3<SbH 3
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    In these hydrides, the group 15 element has an oxidation number of − 3. Other examples of compounds of group 15 elements with varying oxidation states can be seen in the table below. Nitrogen itself can exist in an oxidation state ranging from − 3 to + 5.
    In hydrides, hydrogen is bonded with a highly electronegative atom so their properties are more distinguished. Such that in the chart below comparing boiling points of groups 14-17 hydrides, the values of ammonia (NH 3 ), water (H 2 O), and hydrogen fluoride (HF) break the increasing boiling point trend.
    Figure 4: Boiling Points of Main Group Hydrides. Second, we notice that, with the exceptions of NH 3, H 2 O, and HF, the boiling points of the hydrides always increase in a single group as we go down the periodic table: for example, in Group IV, the boiling points increase in the order CH 4 <SiH 4 <GeH 4 <SnH 4.
  3. What is the order of volatile nature of Group 15 hydrides?

  4. Boiling Points of Simple Hydrides - VIAS

  5. The increasing order of boiling point of hydrides of group 15

  6. Hydrogen Bonding - UCalgary Chemistry Textbook

  7. Chemical Properties of Group 15 Elements: Explanation - EMBIBE

  8. M10Q2: Melting and Boiling Point Comparisons – Chem 103/104 …

  9. Lesson Explainer: Group 15 | Nagwa