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  2. Phosphorus, the Element and Hydrides – Every Science

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    Although phosphorus is adjacent to sulfur in the periodic table, and the predicted phosphorus hydrides have similar covalent bonds with those in sulfur hydrides, phosphorus hydrides are metastable, whereas sulfur hydrides prefer to form stable H 3 S under high pressures.
    We proposed a possible synthesis route for ternary lithium phosphorus hydrides: LiP + H 2 → LiPH n, which could provide helpful and clear guidance to further experimental studies. Our work may provide some advice on further investigations on ternary superconductive hydrides at high pressure.
    Phosphides of transition metals like FeP , CoP , NiP , MoP have been reported as attractive heterogeneous catalysts for the HER in water. On these catalysts, the H 2 evolution is proposed to occur through the metal hydride and the nearby bridging phosphorus hydride .
    Phosphines are compounds that include PH3 and the organophosphines, which are derived from PH3 by substituting one or more hydrogen atoms with organic groups. They have the general formula PH3−nRn. Phosphanes are saturated phosphorus hydrides of the form PnHn+2, such as triphosphane.
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  4. WebPhosphine ( IUPAC name: phosphane) is a colorless, flammable, highly toxic compound with the chemical formula P H 3, classed as a pnictogen hydride. Pure phosphine is odorless, but technical grade samples have a …

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